Neodymium(III) hydride is an inorganic compound composed of neodymium and hydrogen with a chemical formula NdH3.[2][3] In this compound, the neodymium atom is in the +3 oxidation state and the hydrogen atoms are -1. It is highly reactive.[4]
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| Other names
Neodymium(III) hydride
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| Identifiers | |
3D model (JSmol)
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| ChemSpider | |
| ECHA InfoCard | 100.034.177 |
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PubChem CID
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CompTox Dashboard (EPA)
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| Properties | |
| NdH3 | |
| Hazards | |
| GHS labelling:[1] | |
 
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| Danger | |
| H250, H260, H315, H319 | |
| P210, P222, P223, P231, P231+P232, P233, P264, P264+P265, P280, P302+P335+P334, P302+P352, P305+P351+P338, P321, P332+P317, P337+P317, P362+P364, P370+P378, P402+P404, P501 | |
| Related compounds | |
Other anions
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Neodymium(III) oxide Neodymium(III) acetate Neodymium(III) chloride |
Other cations
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europium hydride ytterbium hydride |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Preparation
editNeodymium(III) hydride can be produced by directly reacting neodymium and hydrogen gas:[5]
- 2Nd + 3H2 → 2NdH3
It can also be made by hydrogenerating neodymium(II) hydride.[6]
Properties
editNeodymium hydride is a blue crystal of the hexagonal system, with unit cell parameters a=0.385 nm, c=0.688 nm.[7]
It reacts with water to form neodymium hydroxide and hydrogen gas:[8]
- NdH3 + 3 H2O → Nd(OH)3 + 3 H2
See also
editReferences
edit- ^ "Neodymium hydride (NdH3)". pubchem.ncbi.nlm.nih.gov. Retrieved 26 March 2022.
- ^ Химия и технология редких и рассеянных элементов, ч. II. М.: Высш. школа. 1976.
{{cite book}}: Unknown parameter|agency=ignored (help) - ^ Диаграммы состояния двойных металлических систем. Vol. 1. М.: Машиностроение. 1996. ISBN 5-217-02688-X.
{{cite book}}: Unknown parameter|agency=ignored (help) - ^ The 5f3 vs. 4f3. Routes to and properties of highly reactive neodymium(III) hydrocarbyl and hydride complexes Heiko Mauermann, Paul N. Swepston, and Tobin J. Marks Organometallics 1985 4 (1), 200-202 DOI: 10.1021/om00120a036
- ^ Richter, Bo; Grinderslev, Jakob B.; Møller, Kasper T.; Paskevicius, Mark; Jensen, Torben R. (Aug 23, 2018). "From Metal Hydrides to Metal Borohydrides". Inorganic Chemistry. 57 (17). American Chemical Society (ACS): 10768–10780. doi:10.1021/acs.inorgchem.8b01398. ISSN 0020-1669. PMID 30137973. S2CID 52077203.
- ^ Fukai, Y. (2005). The Metal-Hydrogen System, Basic Bulk Properties, 2d edition. Springer. ISBN 978-3-540-00494-3.
- ^ Peterson, D. T.; Poskie, T. J.; Straatmann, J. A. (1971-02-01). "Neodymium-neodymium hydride phase system". Journal of the Less Common Metals. 23 (2): 177–183. doi:10.1016/0022-5088(71)90078-6. ISSN 0022-5088.
- ^ Widerøe, Marius; Fjellvåg, Helmer; Norby, Truls; Willy Poulsen, Finn; Willestofte Berg, Rolf (2011-07-01). "NdHO, a novel oxyhydride". Journal of Solid State Chemistry. 184 (7): 1890–1894. Bibcode:2011JSSCh.184.1890W. doi:10.1016/j.jssc.2011.05.025. ISSN 0022-4596.