Trimethylolpropane triacrylate (TMPTA) is a trifunctional acrylate ester monomer derived from trimethylolpropane, used in the manufacture of plastics, adhesives, acrylic glue, anaerobic sealants, and ink. It is useful for its low volatility and fast cure response. It has the properties of weather, chemical and water resistance, as well as good abrasion resistance. End products include alkyd coatings,[1] compact discs, hardwood floors, concrete and cementitious applications,[2][3][4] Dental composites, photolithography, letterpress, screen printing, elastomers, automobile headlamps, acrylics and plastic components for the medical industry.
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| Names | |
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| Preferred IUPAC name
2-Ethyl-2-{[(prop-2-enoyl)oxy]methyl}propane-1,3-diyl di(prop-2-enoate) | |
| Identifiers | |
3D model (JSmol)
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| ChemSpider | |
| ECHA InfoCard | 100.036.077 |
PubChem CID
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| UNII | |
CompTox Dashboard (EPA)
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| Properties | |
| C15H20O6 | |
| Molar mass | 296.319 g·mol−1 |
| Density | 1.06 |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Other uses
editAs the molecule has acrylic functionality, it is capable of doing the Michael reaction with an amine. This allows its use in epoxy chemistry where its use speeds up the cure time considerably[5][6]
See also
editReferences
edit- ^ Wang, Qianhe (January 2019). "PhD Dissertation Acrylated Alkyds". University of Akron.
- ^ Rengaraju, Sripriya; Al-Tabbaa, Abir (2023). "Life Cycle Assessment (LCA) of Microcapsule based self-healing in concrete". MATEC Web of Conferences. 378: 06004. doi:10.1051/matecconf/202337806004. ISSN 2261-236X.
- ^ Lin, Xiuju; Liao, Bing; Zhang, Jingfei; Li, Simin; Huang, Jianheng; Pang, Hao (2019-06-20). "Synthesis and characterization of high-performance cross-linked polycarboxylate superplasticizers". Construction and Building Materials. 210: 162–171. doi:10.1016/j.conbuildmat.2019.03.185. ISSN 0950-0618. S2CID 139394654.
- ^ Ma, Yihan; Lei, Lei; Sha, Shengnan; Liu, Yi; Shi, Caijun (2023-06-01). "Synthesis of a cross-linked polycarboxylate ether superplasticizer and its effects on the properties of cement paste containing montmorillonite". Cement and Concrete Research. 168: 107136. doi:10.1016/j.cemconres.2023.107136. ISSN 0008-8846. S2CID 257440284.
- ^ "Epoxy Polyacrylate Resins". www.hexion.com. Retrieved 2020-02-12.
- ^ "Low Viscosity, Fast Curing Epoxy Acrylate Oligomers". www.pcimag.com. Retrieved 2020-02-12.
- TRIMETHYLOLPROPANE TRIACRYLATE at chemicalland21.com
- Trimethylolpropane Triacrylate at OSHA
- Trimethylolpropane triacrylate CAS Number: 15625-89-5 at ntp.niehs.nih.gov