- Group 1
| Pos | Team | Pld | W | D | L | GF | GA | GD | Pts | Qualification[a] | 
|
|
| |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 1 | Netherlands
|
4 | 2 | 1 | 1 | 8 | 4 | +4 | 7[b] | Qualification for Nations League Finals | — | 2–0 | 3–0 | |
| 2 | France
|
4 | 2 | 1 | 1 | 4 | 4 | 0 | 7[b] | 2–1 | — | 2–1 | ||
| 3 | Germany
|
4 | 0 | 2 | 2 | 3 | 7 | −4 | 2 | 2–2 | 0–0 | — |
- ^ Due to revamp of the format for the 2020–21 UEFA Nations League, no teams were eventually relegated.
- ^ a b Head-to-head goal difference: Netherlands +1, France −1.
- Group 2
| Pos | Team | Pld | W | D | L | GF | GA | GD | Pts | Qualification[a] | 
|
|
| |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 1 | Switzerland
|
4 | 3 | 0 | 1 | 14 | 5 | +9 | 9[b] | Qualification for Nations League Finals | — | 5–2 | 6–0 | |
| 2 | Belgium
|
4 | 3 | 0 | 1 | 9 | 6 | +3 | 9[b] | 2–1 | — | 2–0 | ||
| 3 | Iceland
|
4 | 0 | 0 | 4 | 1 | 13 | −12 | 0 | 1–2 | 0–3 | — |
- ^ Due to revamp of the format for the 2020–21 UEFA Nations League, no teams were eventually relegated.
- ^ a b Head-to-head goal difference: Switzerland +2, Belgium −2.
- Group 3
| Pos | Team | Pld | W | D | L | GF | GA | GD | Pts | Qualification[a] | 
|
|
| |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 1 | Portugal
|
4 | 2 | 2 | 0 | 5 | 3 | +2 | 8 | Qualification for Nations League Finals | — | 1–0 | 1–1 | |
| 2 | Italy
|
4 | 1 | 2 | 1 | 2 | 2 | 0 | 5 | 0–0 | — | 1–1 | ||
| 3 | Poland
|
4 | 0 | 2 | 2 | 4 | 6 | −2 | 2 | 2–3 | 0–1 | — |
- ^ Due to revamp of the format for the 2020–21 UEFA Nations League, no teams were eventually relegated.
- Group 4
| Pos | Team | Pld | W | D | L | GF | GA | GD | Pts | Qualification[a] | 
|
|
| |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 1 | England
|
4 | 2 | 1 | 1 | 6 | 5 | +1 | 7 | Qualification for Nations League Finals | — | 1–2 | 2–1 | |
| 2 | Spain
|
4 | 2 | 0 | 2 | 12 | 7 | +5 | 6 | 2–3 | — | 6–0 | ||
| 3 | Croatia
|
4 | 1 | 1 | 2 | 4 | 10 | −6 | 4 | 0–0 | 3–2 | — |
- ^ Due to revamp of the format for the 2020–21 UEFA Nations League, no teams were eventually relegated.