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Look up Sampayo in Wiktionary, the free dictionary.
Sampayo is a surname. Notable people with the surname include:
- Ben Sampayo (born 1992), British footballer
- Carlos Sampayo (born 1943), Argentine writer
- Ramón Sampayo Ortiz (born 1957), Mexican politician
- Thomas Edward de Sampayo (1855-1927), Puisne Justice of the Supreme Court of Sri Lanka