Gadolinium phosphide is an inorganic compound of gadolinium and phosphorus with the chemical formula GdP.[1][2]
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| Names | |
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| Other names
Gadolinium monophosphide, phosphanylidynegadolinium
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| Identifiers | |
3D model (JSmol)
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| EC Number |
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PubChem CID
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| Properties | |
| GdP | |
| Molar mass | 188.22 g·mol−1 |
| Appearance | crystals |
| Density | 6.68 g/cm3 |
| Structure | |
| Cubic | |
| Fm3m | |
| Related compounds | |
Other anions
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Gadolinium nitride Gadolinium arsenide Gadolinium antimonide Gadolinium bismuthide |
Other cations
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Europium phosphide Terbium phosphide |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Synthesis
editGadolinium phosphide can be obtained by reacting gadolinium and phosphorus at high temperature, and single crystals can be obtained by mineralization.[3]
- 4 Gd + P4 → 4 GdP
Physical properties
editGdP has a NaCl-structure and transforms to a CsCl-structure at 40 GPa.[4]
GdP forms crystals of a cubic system, space group Fm3m.[5][6]
Gadolinium phosphide is antiferromagnetic.[citation needed]
Uses
editThe compound is a semiconductor used in high power, high frequency applications and in laser diodes.[1][7]
References
edit- ^ a b "Gadolinium Phosphide". American Elements. Retrieved 9 January 2022.
- ^ "Characteristics of gadolinium monophosphide". Russian Journal of Inorganic Chemistry. 16 (Part 2). British Library Lending Division with the cooperation of the Royal Society of Chemistry: 940. 1971. Retrieved 9 January 2022.
- ^ Li, D. X.; Haga, Y.; Shida, H.; Suzuki, T.; Kwon, Y. S. (15 October 1996). "Electrical transport properties of semimetallic GdX single crystals (X=P, As, Sb, and Bi)". Physical Review B. 54 (15): 10483–10491. Bibcode:1996PhRvB..5410483L. doi:10.1103/PhysRevB.54.10483. PMID 9984843. Retrieved 9 January 2022.
- ^ Adachi, Takafumi; Shirotani, Ichimin; Hayashi, Junichi; Shimomura, Osamu (28 December 1998). "Phase transitions of lanthanide monophosphides with NaCl-type structure at high pressures". Physics Letters A. 250 (4): 389–393. Bibcode:1998PhLA..250..389A. doi:10.1016/S0375-9601(98)00840-8. ISSN 0375-9601. Retrieved 9 January 2022.
- ^ "Gadolinium Phosphide GdP". materialsproject.org. Retrieved 9 January 2022.
- ^ Donnay, Joseph Désiré Hubert (1978). Crystal Data: Inorganic compounds 1967-1969. National Bureau of Standards. p. 75. Retrieved 9 January 2022.
- ^ Lone, Ikram Un Nabi; Sirajuddeen, M. Mohamed Sheik; Khalid, Saubia; Raza, Hafiz Hamid (May 2021). "First-Principles Study on Electronic, Magnetic, Optical, Mechanical, and Thermodynamic Properties of Semiconducting Gadolinium Phosphide in GGA, GGA+U, mBJ, GGA+SOC and GGA+SOC+U approaches". Journal of Superconductivity and Novel Magnetism. 34 (5): 1523–1538. doi:10.1007/s10948-021-05877-z. PMC 8019481. PMID 33841054. Retrieved 9 January 2022.