Deuterated dimethylformamide ((CD3)2NCOD), also known as deuterated DMF, is an isotopologue of DMF ((CH3)2NCOH) in which the hydrogen atom ("H") is replaced with a deuterium isotope ("D"). Deuterated DMF is a relatively uncommon solvent used in NMR spectroscopy.[1][2]
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Names | |||
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IUPAC name
1-Deuterio-N,N-bis(trideuteriomethyl)formamide[citation needed]
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Other names
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Identifiers | |||
3D model (JSmol)
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Abbreviations | DMF-d7[citation needed] | ||
1908468 | |||
ChemSpider | |||
ECHA InfoCard | 100.022.497 | ||
EC Number |
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PubChem CID
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UN number | 2265 | ||
CompTox Dashboard (EPA)
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Properties | |||
C 32 H 7NO or C 3D 7NO | |||
Molar mass | 80.1369 g mol−1 | ||
Appearance | Colourless liquid | ||
Density | 1.03 g mL−1 | ||
Boiling point | 153 °C (307 °F; 426 K) | ||
Refractive index (nD)
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1.428 | ||
Hazards | |||
GHS labelling: | |||
Danger | |||
H312, H319, H332, H360 | |||
P280, P305+P351+P338, P308+P313 | |||
Flash point | 58 °C (136 °F; 331 K) | ||
Explosive limits | 2.2–15.2% | ||
Lethal dose or concentration (LD, LC): | |||
LD50 (median dose)
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Related compounds | |||
Related alkanamides
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Related compounds
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Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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References
edit- ^ Walker, Lynn M.; Wagner, Norman J. (1996-01-01). "SANS Analysis of the Molecular Order in Poly(γ-benzyl l -glutamate)/Deuterated Dimethylformamide (PBLG/d-DMF) under Shear and during Relaxation". Macromolecules. 29 (6): 2298–2301. doi:10.1021/ma951127p. ISSN 0024-9297.
- ^ Kim, Ahran; Kim, Cheal (2019-05-14). "A hydrazono-quinoline-based chemosensor sensing In3+ and Zn2+via fluorescence turn-on and ClO−via color change in aqueous solution". New Journal of Chemistry. 43 (19): 7320–7328. doi:10.1039/C9NJ00899C. ISSN 1369-9261. S2CID 132588760.