A chloride sulfite or sulfite chloride is a chemical compound that contains chloride and sulfite anions (SO32− Cl−). The known compounds of this type are all late transition metal sulfito complexes. Chlorine may be present as a ligand (chloro) or as an ion (chloride). The sulfito ligand can connect to the metal atom by way of an oxygen, or a sulfur atom. It can also link to the metal atom using two oxygen atoms as a bidentate ligand.
Chloride sulfites are not to be confused with the chlorosulfites, which are compounds containing the SO2Cl− ion or -SO2Cl group in organic compounds, where it is also called chlorosulfinate. The chlorosulfates also have the formula SO3Cl− as a single ion, whereas chloride sulfites have three negative charges.
The mercury complex with formula ClHgSO3− is found in the acid gas scrubbers that purify pollution from smokestacks. However it decomposes and does not capture mercury in this application.[1] This complex can form an ammonium salt: ammonium chlorosulfitomercurate(II) NH4[ClHgSO3], which decomposes over 130°C. The salt is formed from mercuric chloride and ammonium sulfite water solutions.[2]
List
edit| name | formula | ratio
SO3:Cl |
mw | system | space group | unit cell | volume | density | optical | references |
|---|---|---|---|---|---|---|---|---|---|---|
| chlorosulfito bis-(1,2-diaminopropane)cobalt(III) monohydrate | Co(NH2CH2CH2CH2NH2)2(SO3)Cl·H2O | 1:1 | red brown | [3] | ||||||
| chlorosulfito bis-(1,2-diaminopropane)cobalt(III) tetrahydrate sodium chloride | Co(NH2CH2CH2CH2NH2)2(SO3)Cl·4H2O·NaCl | 1:1 | brown | [3] | ||||||
| chlorosulfito (1,2-diaminopropane)(ethylenediamine)cobalt(III) monohydrate sodium chloride | Co(NH2CH2CH2CH2NH2)(NH2CH2CH2NH2)(SO3)Cl·H2O·NaCl | 1:1 | brick red | [3] | ||||||
| chlorosulfito bis-(ethylenediamine)cobalt(III) monohydrate | [Co(NH2CH2CH2NH2)2(SO3)Cl]·H2O | 1:1 | pink brown | [4] | ||||||
| ammino sulfito bis-(ethylenediamine)cobalt(III) chloride | [Co(NH2CH2CH2NH2)2(SO3)NH3]Cl | yellow brown | [4] | |||||||
| sulfito bis-(ethylenediamine)cobalt(III) chloride | [Co(NH2CH2CH2NH2)2(SO3)]Cl | brown-red | [4] | |||||||
| sulfito tetraammino chloro osmium | OsSO3(NH3)4Cl | 1:1 | pink brown | [5] | ||||||
| Na6[Os(SO3)4Cl2]·10H2O | 4:2 | purple | [6] | |||||||
| Na7[Os(SO3)5Cl]·6H2O | 5:1 | pale violet | [6] | |||||||
| K8[Os(SO3)4Cl4] | 4:4 | brown | [6] | |||||||
| sulfito aquo octaammino μ-nitrido diosmium trichloride | [Os2N(SO3)(NH3)8H2O]Cl3 | 1:3 | yellow brown | [5] | ||||||
| Na2[Ir(SO3)2(NH4)3Cl] | 2:1 | [7][8] | ||||||||
| trisodium diaquadichlorodisulfitoiridate(III) heptahydrate | Na3[IrCl2(SO3)2(OH2)2]·7H2O | Pnma | Z=4 | yellow | [9] | |||||
| trisodium disulfito dichloro diammino iridium tetrahydrate | Na3[Ir(SO3)2(NH4)2Cl2]·4H2O | 2:2 | [5] | |||||||
| trisodium disulfito dichloro diammino iridium hexahydrate | Na3[Ir(SO3)2(NH4)2Cl2]·6H2O | 2:2 | pale yellow | [5] | ||||||
| tripotassium diaquadichlorodisulfitoiridate(III) dihydrate | K3[IrCl2(SO3)2(OH2)2]·2H2O | C2 | Z=2 | yellow | [9] | |||||
| Na5[Ir(SO3)2Cl4] | 2:4 | [7] | ||||||||
| pentapotassium disulfito tetrachloro iridium hexahydrate | K5[Ir(SO3)2Cl4]·6H2O | light orange | [5] | |||||||
| pentasodium dichlorobis(hydrogendisulfito)iridate(III) | trans-Na5[IrCl2{(SO3H)(SO3)}2]·10H2O | C2/c | pale yellow | [9] | ||||||
| pentapotassium dichlorobis(hydrogendisulfito)iridates(III) | trans-K5[IrCl2{(SO3H)(SO3)}2]·5H2O | pale yellow | [9] | |||||||
| Na7[Ir(SO3)4Cl2] | 4:2 | [7] | ||||||||
| hepta sodium tetrasulfito dichloro iridium heptahydrate | Na7[Ir(SO3)4Cl2]·7H2O | pale yellow | [5] | |||||||
| K7[Ir(SO3)2(NO3)2Cl] | 4:2 | [7][10] | ||||||||
| (NH4)5lr(SO3)2Cl4 | 2:4 | monoclinic | P21/n | a = 11.10 b = 7.25 c = 7.25 β= 96.5 Z = 2 | [11] | |||||
| (NH4)4lr(SO3)2Cl3·4H2O | 2:3 | monoclinic | a = 10.44 b = 9.46 c = 7.48 β = 90.5, Z = 2 | [11] | ||||||
| NH4[ClHgSO3] | 1:1 | Pnma | a=15.430 b=5.525 c=6.679 Z=4 | [2] | ||||||
| K[HgSO3Cl]·KCl·H2O | 1:2 | 761.18 | triclinc | P1_ | a = 6.1571 b = 7.1342 c = 10.649 α = 76.889, β = 88.364, γ = 69.758° Z=4 | 426.8 | 4.358 | [12] | ||
| K[HgSO3Cl]·KCl·HgCl2 | 1:4 | 701.24 | monoclinic | P21/m | a=9.532 b=5.9593 c=10.176 β =110.522 Z=2 | 541.3 | 4.302 | [12] | ||
| K[HgSO3Cl]·HgCl2 | 1:3 | 626.69 | orthorhombic | Cmc21 | a=5.9313 b=21.746 c=6.7899 Z=4 | 879.79 | 4.753 | [12] | ||
| NH4[HgSO3Cl]·HgCl2 | 1:3 | 605.65 | orthorhombic | Cmc21 | a=5.962 b=22.247 c=6.958 Z=4 | 923.0 | 4.358 | [12] | ||
| NH4[HgSO3Cl]·HgCl2·NH4Cl | 1:4 | 659.12 | monoclinic | P21/m | a=9.712 b=6.138 c=10.401 β =110.92 Z=2 | 579.2 | 3.779 | [12] | ||
| (K[HgSO3Cl])2·KCl·HgCl2 | 2:5 | 1056.44 | orthorhombic | Pnma | a=22.158 b=5.9736 c=12.249 Z=4 | 1621.2 | 4.328 | [12] |
References
edit- ^ Senior, Constance (October 2007). "Review of the Role of Aqueous Chemistry in Mercury Removal by Acid Gas Scrubbers on Incinerator Systems". Environmental Engineering Science. 24 (8): 1129–1134. doi:10.1089/ees.2007.0105.
- ^ a b Weil, Matthias; Breitinger, Dietrich K.; Liehr, Günther; Zürbig, Jürgen (March 2007). "Structural Investigations and Thermal Behaviour of Mercury(II) Sulfito Complexes". Zeitschrift für anorganische und allgemeine Chemie. 633 (3): 429–434. doi:10.1002/zaac.200600313.
- ^ a b c Salib, Kamal A. R.; Abu El-Wafa, Samy M.; El-Maraghy, Salah B.; El-Sayed, Saied M. (December 1989). "Sulfitoamine Complexes of Cobalt(III)". Phosphorus, Sulfur, and Silicon and the Related Elements. 46 (3–4): 131–138. doi:10.1080/10426508909412058. ISSN 1042-6507.
- ^ a b c Baldwin, M. E. (1961). "599. Sulphitobis(ethylenediamine)cobalt(III) complexes". Journal of the Chemical Society (Resumed): 3123–3128. doi:10.1039/jr9610003123. ISSN 0368-1769.
- ^ a b c d e f Hall, J.P.; Griffith, W.P. (January 1981). "Vibrational spectra of group VIII sulphito complexes". Inorganica Chimica Acta. 48: 65–71. doi:10.1016/S0020-1693(00)90068-9.
- ^ a b c Livingstone, Stanley E. (2017-01-31). The Chemistry of Ruthenium, Rhodium, Palladium, Osmium, Iridium and Platinum: Pergamon Texts in Inorganic Chemistry, Volume 25. Elsevier. p. 1229. ISBN 978-1-4831-5840-2.
- ^ a b c d Livingstone, Stanley E. (2017). The Chemistry of Ruthenium, Rhodium, Palladium, Osmium, Iridium and Platinum: Pergamon Texts in Inorganic Chemistry, Volume 25. Elsevier. p. 1265. ISBN 978-1-4831-5840-2.
- ^ Ferrari, A., and C. Colla. "Iridionitrites of ammonium, potassium, rubidium, cæsium and thallium." Gazzetta Chimica Italiana 63 (1933): 507-513
- ^ a b c d Breitinger, D.K; Bogner, A (May 1999). "Vibrational spectra of sulfito and hydrogensulfito complexes of iridium". Journal of Molecular Structure. 482–483 (1–3): 125–129. Bibcode:1999JMoSt.482..125B. doi:10.1016/S0022-2860(98)00635-8.
- ^ russ j inor chem 6 1961 1247
- ^ a b Porai-Koshits, M. A.; Ionov, S. P.; Novozhenyuk, Z. M. (1965). "Crystal structure of some trivalent iridium compounds containing sulfite groups in the complex ion". Journal of Structural Chemistry. 6 (1): 161–162. doi:10.1007/BF00743893. ISSN 0022-4766. S2CID 98609854.
- ^ a b c d e f Weil, Matthias; Baumann, Stefan; Breitinger, Dietrich K. (August 2008). "Structural Studies of New Sulfito Mercurates(II) with General Formula xM [ X HgSO 3 ]middot; y Hg X 2 · zM X· n H 2 O ( M = NH 4 , K; X = Cl, Br)". Zeitschrift für anorganische und allgemeine Chemie. 634 (10): 1742–1748. doi:10.1002/zaac.200800159.