Calmagite is a complexometric indicator used in analytical chemistry to identify the presence of metal ions in solution. As with other metal ion indicators calmagite will change color when it is bound to an ion. Calmagite will be wine red when it is bound to a metal ion and may be blue, red, or orange when it is not bound to a metal ion. Calmagite is often used in conjunction with EDTA, a stronger metal binding agent.[2] This chemical is also used in the quantitation of magnesium in the clinical laboratory.

Calmagite[1]
Skeletal formula
Ball-and-stick model
Names
IUPAC name
3-Hydroxy-4-[(2-hydroxy-5-methylphenyl)azo]-1-naphthalenesulfonic acid
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.019.603 Edit this at Wikidata
UNII
  • InChI=1/C17H14N2O5S/c1-10-6-7-14(20)13(8-10)18-19-17-12-5-3-2-4-11(12)16(9-15(17)21)25(22,23)24/h2-9,20-21H,1H3,(H,22,23,24)
    Key: VBRNLOQCBCPPHL-UHFFFAOYAD
  • Oc3ccc(C)cc3N=Nc2c1ccccc1c(cc2O)S(O)(=O)=O
Properties
C17H14N2O5S
Molar mass 358.37 g·mol−1
Appearance Red to black crystals
Odor Phenolic odor
Melting point 330 °C (626 °F; 603 K)
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
May emit ammonia, oxides of sulfur, oxides of nitrogen, and oxides of carbon.
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

References

edit
  1. ^ Calmagite at Sigma-Aldrich
  2. ^ Harris, Daniel C. Quantitative Chemical Analysis, W.H. Freeman and Company ,2007. ISBN 0-7167-7041-5