Wikipedia

Andrei Khlobystov

Andrei Nikolaevich Khlobystov (Russian: Андрей Николаевич Хлобыстов) is a Russian-British scientist who is the Professor of Nanomaterials at the University of Nottingham. He serves as Director for Research for the School of Chemistry in the Faculty of Science and has received several awards during his career, including the European Young Investigator award[1] and the Corday–Morgan Prize in 2015.[2] Khlobystov is currently the Director and principal investigator of the Metal Atoms on Surfaces and Interfaces EPSRC Programme Grant.

Andrei Khlobystov
Born1974 (age 49–50)
Alma mater
Scientific career
Fields
Institutions
Doctoral advisorMartin Schröder

Early life and education

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Andrei Nikolaevich Khlobystov was born in Soviet Russia in 1974. He obtained a Master of Science degree in chemistry from Moscow State University in 1997, and received a PhD in 2002 from the University of Nottingham under the supervision of Martin Schröder and Neil Champness.[3][4][5]

Career and research

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Khlobystov started his post-doctoral career at the Department of Materials at the University of Oxford from 2002 until 2004 under Andrew Briggs, where he began exploring carbon nanotube as nanoscale containers for molecules.[6] He applied transmission electron microscopy (TEM) for imaging structures of individual molecules and studying their dynamic behaviour in direct space and real time, which shed light on intermolecular interactions, and the translation and rotational motion of molecules at nanoscale. He was part of the team awarded a Guinness World Record for performing a chemical reaction inside carbon nanotubes.[7][8]

In 2004, Khlobystov moved to the University of Nottingham as a Leverhulme Trust research fellow.[9] At Nottingham, he built the Nottingham Nanocarbon Group, which has demonstrated that nanoscale confinement can lead to new products inaccessible by other synthetic methods.[10] In 2005, his research group was awarded a European Young Investigator award and a Royal Society University Research Fellowship.[11][12] Around this time, he was featured in Times Higher Education's series of emerging researchers in the physical sciences.[13] In 2008, the Nanocarbon Group presented at the Royal Society's Summer Science Exhibition, with a display entitled "Wonder in carbon land: how do you hold a molecule?", showcasing the potential of utilising nanocages and nanotubes to control chemical reactions.[14] Khlobystov's team has discovered mechanisms of interactions between carbon nanostructures and molecules or nanoparticles which enabled the design of nanoreactor systems with tuneable size and functionality.[15][16] This research was supported by numerous grants including a European Research Council Starting Grant in 2011.[17]

In 2016, to commemorate the opening of the nano- and micro-Research Centre (nmRC) at the University of Nottingham, Khlobystov led a team that utilised a Focused Ion Beam Scanning Electron Microscope (FIB-SEM) to etch a birthday message onto a corgi hair to commemorate Queen Elizabeth II's 90th birthday.[18][19] In 2020, Khlobystov led a team that captured a video of the chemical bond between two metal atoms breaking and forming for the first time.[20] This followed previous work which embraced the observer effect, utilising the electron beam present in an electron microscopy to provide the source of energy to drive chemical reactions and enable them to be directly observed, and was given the moniker ChemTEM.[21][22]

Since 2021, Khlobystov has been PI for the MASI programme grant, which is investigating solvent-free routes to preparing and understanding single metal atoms and metal nanoclusters on surfaces for use as catalysts for electrochemical hydrogen production, ammonia synthesis and carbon dioxide reduction.[23]

References

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  1. ^ "2005 : European Science Foundation". archives.esf.org. Retrieved 31 October 2023.
  2. ^ "Royal Society of Chemistry Prizes and Awards 2015". 20 February 2016. Archived from the original on 20 February 2016. Retrieved 30 October 2023.
  3. ^ Blake, Alexander J.; Champness, Neil R.; Khlobystov, Andrei; Li, Wan-Sheung; Schröder, Martin; Khlobystov, Andrei; Lemenovskii, Dmitri A. (1 January 1997). "Polycatenated copper(I) molecular ladders: a new structural motif in inorganic coordination polymers". Chemical Communications (21): 2027–2028. doi:10.1039/A705853E. ISSN 1364-548X.
  4. ^ Khlobystov, Andrei N.; Champness, Neil R.; Roberts, Clive J.; Tendler, Saul J. B.; Thompson, Claire; Schröder, Martin (7 August 2002). "Anion exchange in co-ordination polymers: a solid-state or a solvent-mediated process?". CrystEngComm. 4 (71): 426–431. doi:10.1039/B202217F. ISSN 1466-8033.
  5. ^ "Andrei Khlobystov". www.nottingham.ac.uk. Retrieved 8 June 2024.
  6. ^ Khlobystov, A.N.; Porfyrakis, K.; Britz, D.A.; Kanai, M.; Scipioni, R.; Lyapin, S.G.; Wiltshire, J.G.; Ardavan, A.; Nguyen-Manh, D.; Nicholas, R.J.; Pettifor, D.G.; Dennis, T.J.S.; Briggs, G.A.D. (August 2004). "Ordering and interaction of molecules encapsulated in carbon nanotubes". Materials Science and Technology. 20 (8): 969–974. Bibcode:2004MatST..20..969K. doi:10.1179/174328413X13789824293425. ISSN 0267-0836. S2CID 136481665.
  7. ^ "Smallest test tube (open-ended) - Guinness World Records". Retrieved 31 October 2023.
  8. ^ Rincon, Paul (24 November 2004). "Tiny carbon cylinders set record". BBC. Retrieved 8 June 2024.
  9. ^ Khlobystov, Andrei N. (27 December 2011). "Carbon Nanotubes: From Nano Test Tube to Nano-Reactor". ACS Nano. 5 (12): 9306–9312. doi:10.1021/nn204596p. ISSN 1936-0851. PMID 22200191.
  10. ^ "Molecules in Carbon Nanotubes". 2 June 2005. Retrieved 1 November 2023.
  11. ^ "Andrei Khlobystov : European Science Foundation". archives.esf.org. Retrieved 30 October 2023.
  12. ^ "Careers". Chemistry World. Retrieved 30 October 2023.
  13. ^ "Excited by the wonders of our material world". Times Higher Education (THE). 25 August 2006. Retrieved 30 October 2023.
  14. ^ "Wonder in carbon land: how do you hold a molecule? | Royal Society". royalsociety.org. Retrieved 31 October 2023.
  15. ^ Miners, Scott A.; Rance, Graham A.; Khlobystov, Andrei N. (22 August 2016). "Chemical reactions confined within carbon nanotubes". Chemical Society Reviews. 45 (17): 4727–4746. doi:10.1039/C6CS00090H. ISSN 1460-4744. PMID 27301444.
  16. ^ "Peering into private life of atomic clusters -- using the world's tiniest test tubes". EurekAlert!. Retrieved 1 November 2023.
  17. ^ "ERC Starting Grants 2011 Results Physical Sciences" (PDF). Retrieved 31 October 2023.
  18. ^ "Queen's tiny 90th birthday message etched on corgi hair". BBC News. 21 April 2016. Retrieved 30 October 2023.
  19. ^ "Notts experts etch microscopic Queen's birthday message onto a strand of Corgi hair". NottsTV.
  20. ^ "Watch the first ever video of a chemical bond breaking and forming". New Scientist. Retrieved 30 October 2023.
  21. ^ "Caught on camera -- chemical reactions 'filmed' at the single-molecule level". EurekAlert!. Retrieved 30 October 2023.
  22. ^ Skowron, Stephen T.; Chamberlain, Thomas W.; Biskupek, Johannes; Kaiser, Ute; Besley, Elena; Khlobystov, Andrei N. (15 August 2017). "Chemical Reactions of Molecules Promoted and Simultaneously Imaged by the Electron Beam in Transmission Electron Microscopy". Accounts of Chemical Research. 50 (8): 1797–1807. doi:10.1021/acs.accounts.7b00078. ISSN 1520-4898. PMID 28696097.
  23. ^ Popov, Ilya; Ghaderzadeh, Sadegh; Kohlrausch, Emerson C.; Norman, Luke T.; Slater, Thomas J. A.; Aliev, Gazi N.; Alhabeadi, Hanan; Kaplan, Andre; Theis, Wolfgang; Khlobystov, Andrei N.; Fernandes, Jesum Alves; Besley, Elena (13 September 2023). "Chemical Kinetics of Metal Single Atom and Nanocluster Formation on Surfaces: An Example of Pt on Hexagonal Boron Nitride". Nano Letters. 23 (17): 8006–8012. Bibcode:2023NanoL..23.8006P. doi:10.1021/acs.nanolett.3c01968. ISSN 1530-6984. PMC 10510580. PMID 37594260.
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