(Terpyridine)ruthenium trichloride

(Terpyridine)ruthenium trichloride
Identifiers
CAS Number	72905-30-7 ;
3D model (JSmol)	Interactive image;
ChemSpider	9179899;
PubChem CID	11004708;
	InChI InChI=1S/C15H11N3.3ClH.Ru/c1-3-10-16-12(6-1)14-8-5-9-15(18-14)13-7-2-4-11-17-13;;;;/h1-11H;3*1H;/q;;;;+3/p-3 Key: YDKDTFLOHRMCRP-UHFFFAOYSA-K;
	SMILES c1ccnc(c1)c2cccc(n2)c3ccccn3.[Ru+3].[Cl-].[Cl-].[Cl-];
Properties
Chemical formula	C15H11Cl3N3Ru
Molar mass	440.69 g·mol−1
Appearance	brown solid
Density	1.451 g/cm3
Solubility in water	insoluble
Hazards
	GHS labelling:
Signal word	Warning
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

(Terpyridine)ruthenium trichloride is the coordination complex with the formula RuCl₃(terpy), where terpy is terpyridine. It is a brown paramagnetic solid that is a precursor to other complexes of ruthenium, mainly by substitution of the chloride ligands. The complex has octahedral geometry.^[1] The synthesis of this complex was reported for the first time in 1980, it was prepared by mixing ruthenium trichloride and terpyridine in ethanol, heating the mixture to reflux conditions^[2] A later synthetic protocol uses a similar approach by heating ruthenium trichloride with a DMF solution of terpyridine.^[3]

References

^ Ziegler, Marco; Monney, Véronique; Stoeckli-Evans, Helen; von Zelewsky, Alex; Sasaki, Isabelle; Dupic, Gilles; Daran, Jean-Claude; Balavoine, Gilbert G. A. (1999). "Complexes of New Chiral Terpyridyl Ligands. Synthesis and Characterization of Their Ruthenium(II) and Rhodium(III) Complexes". Journal of the Chemical Society, Dalton Transactions (5): 667–676. doi:10.1039/a900194h.
^ Sullivan, B. Patrick; Calvert, Jeffrey M.; Meyer, Thomas J. (May 1980). "Cis-trans isomerism in (trpy)(PPh3)RuC12. Comparisons between the chemical and physical properties of a cis-trans isomeric pair". Inorganic Chemistry. 19 (5): 1404–1407. doi:10.1021/ic50207a066. ISSN 0020-1669.
^ Bessel, Carol A.; Leising, Randolph A.; Szczepura, Lisa F.; Perez, Willie J.; Vo Huyhn, My Hang; Takeuchi, Kenneth J. (1998). "Trichloro[2,2′:6′,2″-Terpyridine]Ruthenium(III) and Phosphine Ligand Derivatives". Inorganic Syntheses. Vol. 32. p. 186-198. doi:10.1002/9780470132630.ch32. ISBN 9780471249214.

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[1] Ziegler, Marco; Monney, Véronique; Stoeckli-Evans, Helen; von Zelewsky, Alex; Sasaki, Isabelle; Dupic, Gilles; Daran, Jean-Claude; Balavoine, Gilbert G. A. (1999). "Complexes of New Chiral Terpyridyl Ligands. Synthesis and Characterization of Their Ruthenium(II) and Rhodium(III) Complexes". Journal of the Chemical Society, Dalton Transactions (5): 667–676. doi:10.1039/a900194h.

[2] Sullivan, B. Patrick; Calvert, Jeffrey M.; Meyer, Thomas J. (May 1980). "Cis-trans isomerism in (trpy)(PPh3)RuC12. Comparisons between the chemical and physical properties of a cis-trans isomeric pair". Inorganic Chemistry. 19 (5): 1404–1407. doi:10.1021/ic50207a066. ISSN 0020-1669.

[3] Bessel, Carol A.; Leising, Randolph A.; Szczepura, Lisa F.; Perez, Willie J.; Vo Huyhn, My Hang; Takeuchi, Kenneth J. (1998). "Trichloro[2,2′:6′,2″-Terpyridine]Ruthenium(III) and Phosphine Ligand Derivatives". Inorganic Syntheses. Vol. 32. p. 186-198. doi:10.1002/9780470132630.ch32. ISBN 9780471249214.

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Identifiers

CAS Number	72905-30-7^Y
3D model (JSmol)	Interactive image
ChemSpider	9179899
PubChem CID	11004708
InChI InChI=1S/C15H11N3.3ClH.Ru/c1-3-10-16-12(6-1)14-8-5-9-15(18-14)13-7-2-4-11-17-13;;;;/h1-11H;3*1H;/q;;;;+3/p-3 Key: YDKDTFLOHRMCRP-UHFFFAOYSA-K
SMILES c1ccnc(c1)c2cccc(n2)c3ccccn3.[Ru+3].[Cl-].[Cl-].[Cl-]
Properties
Chemical formula	C₁₅H₁₁Cl₃N₃Ru
Molar mass	440.69 g·mol⁻¹
Appearance	brown solid
Density	1.451 g/cm³
Solubility in water	insoluble
Hazards
GHS labelling:
Signal word	Warning
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references