Mercury sulfide, or mercury(II) sulfide is a chemical compound composed of the chemical elements mercury and sulfur. It is represented by the chemical formula HgS. It is virtually insoluble in water.[4]
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| Names | |
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| IUPAC name
Mercury sulfide
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| Other names | |
| Identifiers | |
3D model (JSmol)
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| ECHA InfoCard | 100.014.270 |
| EC Number |
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PubChem CID
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| UNII | |
| UN number | 2025 |
CompTox Dashboard (EPA)
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| Properties | |
| HgS | |
| Molar mass | 232.66 g/mol |
| Density | 8.10 g/cm3 |
| Melting point | 580 °C (1,076 °F; 853 K) decomposes |
| insoluble | |
| Band gap | 2.1 eV (direct, α-HgS) [1] |
| −55.4·10−6 cm3/mol | |
Refractive index (nD)
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w=2.905, e=3.256, bire=0.3510 (α-HgS) [2] |
| Thermochemistry | |
Std molar
entropy (S⦵298) |
78 J·mol−1·K−1[3] |
Std enthalpy of
formation (ΔfH⦵298) |
−58 kJ·mol−1[3] |
| Hazards | |
| GHS labelling: | |
   
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| Danger | |
| H300, H310, H317, H330, H373, H410 | |
| P261, P272, P280, P302+P352, P321, P333+P313, P363, P501 | |
| NFPA 704 (fire diamond) | |
| Flash point | Non-flammable |
| Safety data sheet (SDS) | Fisher Scientific |
| Related compounds | |
Other anions
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Mercury oxide mercury selenide mercury telluride |
Other cations
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Zinc sulfide cadmium sulfide |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Crystal structure
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HgS is dimorphic with two crystal forms:
- red cinnabar (α-HgS, trigonal, hP6, P3221) is the form in which mercury is most commonly found in nature. Cinnabar has rhombohedral crystal system. Crystals of red are optically active. This is caused by the Hg-S helices in the structure.[5]
- black metacinnabar (β-HgS) is less common in nature and adopts the zinc blende crystal structure (T2d-F43m).
Preparation and chemistry
editβ-HgS precipitates as a black solid when Hg(II) salts are treated with H2S. The reaction is conveniently conducted with an acetic acid solution of mercury(II) acetate. With gentle heating of the slurry, the black polymorph converts to the red form.[6] β-HgS is unreactive to all but concentrated acids.[4]
Mercury is produced from the cinnabar ore by roasting in air and condensing the vapour.[4]
- HgS → Hg + S
Uses
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When α-HgS is used as a red pigment, it is known as cinnabar. The tendency of cinnabar to darken has been ascribed to conversion from red α-HgS to black β-HgS. However β-HgS was not detected at excavations in Pompeii, where originally red walls darkened, and was attributed to the formation of Hg-Cl compounds (e.g., corderoite, calomel, and terlinguaite) and calcium sulfate, gypsum.[7]
As the mercury cell as used in the chlor-alkali industry (Castner–Kellner process) is being phased out over concerns over mercury emissions, the metallic mercury from these setups is converted into mercury sulfide for underground storage.
With a band gap of 2.1 eV and its stability, it is possible to be used as photoelectrochemical cell.[8]
See also
edit- Mercury poisoning
- Mercury(I) sulfide (mercurous sulfide, Hg
2S), hypothetical
References
edit- ^ L. I. Berger, Semiconductor Materials (1997) CRC Press ISBN 0-8493-8912-7
- ^ Webminerals
- ^ a b Zumdahl, Steven S. (2009). Chemical Principles 6th Ed. Houghton Mifflin Company. p. A22. ISBN 978-0-618-94690-7.
- ^ a b c Greenwood, Norman N.; Earnshaw, Alan (1984). Chemistry of the Elements. Oxford: Pergamon Press. p. 1406. ISBN 978-0-08-022057-4.
- ^ A. M. Glazer, K. Stadnicka (1986). "On the origin of optical activity in crystal structures". J. Appl. Crystallogr. 19 (2): 108–122. doi:10.1107/S0021889886089823. S2CID 96545158.
- ^ Newell, Lyman C.; Maxson, R. N.; Filson, M. H. (1939). "Red Mercuric Sulfide". Inorganic Syntheses. Vol. 1. pp. 19–20. doi:10.1002/9780470132326.ch7. ISBN 9780470132326.
- ^ Cotte, M; Susini J; Metrich N; Moscato A; Gratziu C; Bertagnini A; Pagano M (2006). "Blackening of Pompeian Cinnabar Paintings: X-ray Microspectroscopy Analysis". Anal. Chem. 78 (21): 7484–7492. doi:10.1021/ac0612224. PMID 17073416.
- ^ Davidson, R. S.; Willsher, C. J. (March 1979). "Mercury(II) sulphide: a photo-stable semiconductor". Nature. 278 (5701): 238–239. doi:10.1038/278238a0. ISSN 1476-4687. S2CID 4363745.