Naturally occurring praseodymium (59Pr) is composed of one stable isotope, 141Pr. Thirty-eight radioisotopes have been characterized with the most stable being 143Pr, with a half-life of 13.57 days and 142Pr, with a half-life of 19.12 hours. All of the remaining radioactive isotopes have half-lives that are less than six hours and the majority of these have half-lives that are less than 33 seconds. This element also has 15 meta states with the most stable being 138mPr (t1/2 2.12 hours), 142mPr (t1/2 14.6 minutes) and 134mPr (t1/2 11 minutes).
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Standard atomic weight Ar°(Pr) | ||||||||||||||||||||||||||||
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The isotopes of praseodymium range in atomic weight from 120.955 u (121Pr) to 158.955 u (159Pr). The primary decay mode before the stable isotope, 141Pr, is electron capture and the mode after is beta decay. The primary decay products before 141Pr are element 58 (cerium) isotopes and the primary products after are element 60 (neodymium) isotopes.
List of isotopes
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Nuclide [n 1] |
Z | N | Isotopic mass (Da)[4] [n 2][n 3] |
Half-life[1] [n 4] |
Decay mode[1] [n 5] |
Daughter isotope [n 6][n 7] |
Spin and parity[1] [n 8][n 4] |
Isotopic abundance | |||||||||||
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Excitation energy[n 4] | |||||||||||||||||||
121Pr | 59 | 62 | 120.95539(54)# | 12(5) ms | p | 120Ce | (3/2)(+#) | ||||||||||||
124Pr | 59 | 65 | 123.94294(43)# | 1.2(2) s | β+ | 124Ce | |||||||||||||
β+, p (?%) | 123La | ||||||||||||||||||
125Pr | 59 | 66 | 124.93766(32)# | 3.3(7) s | β+ | 125Ce | 3/2+# | ||||||||||||
126Pr | 59 | 67 | 125.93524(21)# | 3.12(18) s | β+ | 126Ce | (4, 5) | ||||||||||||
β+, p (?%) | 125La | ||||||||||||||||||
127Pr | 59 | 68 | 126.93071(21)# | 4.2(3) s | β+ | 127Ce | 3/2+# | ||||||||||||
127mPr | 600(200)# keV | 2# μs | (11/2−) | ||||||||||||||||
128Pr | 59 | 69 | 127.928791(32) | 2.85(9) s | β+ | 128Ce | (3+) | ||||||||||||
β+, p (?%) | 127La | ||||||||||||||||||
129Pr | 59 | 70 | 128.925095(32) | 30(4) s | β+ | 129Ce | (3/2+) | ||||||||||||
129mPr | 382.57(24) keV | 26(11)# μs | IT | 129Pr | (11/2−) | ||||||||||||||
130Pr | 59 | 71 | 129.923590(69) | 40.0(4) s | β+ | 130Ce | (6, 7)(+#) | ||||||||||||
130mPr | 100(100)# keV | 10# s | 2+# | ||||||||||||||||
131Pr | 59 | 72 | 130.920235(50) | 1.50(3) min | β+ | 131Ce | (3/2+) | ||||||||||||
131mPr | 152.4(3) keV | 5.73(20) s | IT (96.4%) | 131Pr | (11/2−) | ||||||||||||||
β+ (3.6%) | 131Ce | ||||||||||||||||||
132Pr | 59 | 73 | 131.919240(31) | 1.49(11) min | β+ | 132Ce | (2+) | ||||||||||||
132m1Pr[n 9] | 30(30)# keV | 1# s | (5+) | ||||||||||||||||
132m2Pr | 250(30)# keV | 2.46(4) μs | IT | 132Pr | (8+) | ||||||||||||||
132m3Pr | 300(30)# keV | 486(70) ns | IT | 132Pr | (8−) | ||||||||||||||
133Pr | 59 | 74 | 132.916331(13) | 6.5(3) min | β+ | 133Ce | 5/2+ | ||||||||||||
133mPr | 192.12(14) keV | 1.1(2) μs | IT | 133Pr | (11/2−) | ||||||||||||||
134Pr | 59 | 75 | 133.915697(22) | 17(2) min | β+ | 134Ce | 2− | ||||||||||||
134mPr | 67.7(4) keV | ~11 min | β+ | 134Ce | 6− | ||||||||||||||
135Pr | 59 | 76 | 134.913112(13) | 24(1) min | β+ | 135Ce | 3/2+ | ||||||||||||
135mPr | 358.06(6) keV | 105(10) μs | IT | 135Pr | (11/2−) | ||||||||||||||
136Pr | 59 | 77 | 135.912677(12) | 13.1(1) min | β+ | 136Ce | 2+ | ||||||||||||
137Pr | 59 | 78 | 136.9106792(87) | 1.28(3) h | β+ | 137Ce | 5/2+ | ||||||||||||
137mPr | 561.22(23) keV | 2.66(7) μs | IT | 137Pr | 11/2− | ||||||||||||||
138Pr | 59 | 79 | 137.910757(11) | 1.45(5) min | β+ | 138Ce | 1+ | ||||||||||||
138mPr | 350(19) keV | 2.12(4) h | β+ | 138Ce | 7− | ||||||||||||||
139Pr | 59 | 80 | 138.9089327(39) | 4.41(4) h | β+ | 139Ce | 5/2+ | ||||||||||||
140Pr | 59 | 81 | 139.9090856(66) | 3.39(1) min | EC (51.3%) | 140Ce | 1+ | ||||||||||||
β+ (48.7%) | |||||||||||||||||||
140m1Pr | 127.8(3) keV | 0.35(2) μs | IT | 140Pr | 5+ | ||||||||||||||
140m2Pr | 763.7(5) keV | 3.05(20) μs | IT | 140Pr | (7)− | ||||||||||||||
141Pr[n 10] | 59 | 82 | 140.9076596(16) | Stable | 5/2+ | 1.0000 | |||||||||||||
142Pr | 59 | 83 | 141.9100516(16) | 19.12(4) h | β− (99.98%) | 142Nd | 2− | ||||||||||||
EC (0.0164%) | 142Ce | ||||||||||||||||||
142mPr | 3.694(3) keV | 14.6(5) min | IT | 142Pr | 5− | ||||||||||||||
143Pr[n 10] | 59 | 84 | 142.9108226(19) | 13.57(2) d | β− | 143Nd | 7/2+ | ||||||||||||
144Pr | 59 | 85 | 143.9133107(29) | 17.28(5) min | β− | 144Nd | 0− | ||||||||||||
144mPr | 59.03(3) keV | 7.2(3) min | IT (~99.93%) | 144Pr | 3− | ||||||||||||||
β− (~0.07%) | 144Nd | ||||||||||||||||||
145Pr | 59 | 86 | 144.9145180(77) | 5.984(10) h | β− | 145Nd | 7/2+ | ||||||||||||
146Pr | 59 | 87 | 145.917688(37) | 24.09(10) min | β− | 146Nd | (2−) | ||||||||||||
147Pr | 59 | 88 | 146.919007(17) | 13.39(4) min | β− | 147Nd | 3/2+ | ||||||||||||
148Pr | 59 | 89 | 147.922130(16) | 2.29(2) min | β− | 148Nd | 1− | ||||||||||||
148mPr | 76.80(20) keV | 2.01(7) min | β− (64%) | 148Nd | (4) | ||||||||||||||
IT (36%) | 148Pr | ||||||||||||||||||
149Pr | 59 | 90 | 148.923736(11) | 2.26(7) min | β− | 149Nd | (5/2+) | ||||||||||||
150Pr | 59 | 91 | 149.9266764(97) | 6.19(16) s | β− | 150Nd | 1− | ||||||||||||
151Pr | 59 | 92 | 150.928309(13) | 18.90(7) s | β− | 151Nd | (3/2−) | ||||||||||||
151mPr | 35.10(10) keV | 50(8) μs | IT | 151Pr | (7/2+) | ||||||||||||||
152Pr | 59 | 93 | 151.931553(20) | 3.57(11) s | β− | 152Nd | 4+ | ||||||||||||
152mPr | 115.1(3) keV | 4.16(10) μs | IT | 152Pr | (1+) | ||||||||||||||
153Pr | 59 | 94 | 152.933904(13) | 4.28(11) s | β− | 153Nd | 3/2−# | ||||||||||||
154Pr | 59 | 95 | 153.93789(11) | 2.30(9) s | β− | 154Nd | (3+) | ||||||||||||
155Pr | 59 | 96 | 154.940509(18) | 1.47(3) s | β− | 155Nd | 3/2−# | ||||||||||||
156Pr | 59 | 97 | 155.9447669(11) | 444(6) ms | β− | 156Nd | 1+# | ||||||||||||
157Pr | 59 | 98 | 156.9480031(34) | 307(21) ms | β− | 157Nd | 3/2−# | ||||||||||||
158Pr | 59 | 99 | 157.95260(32)# | 181(14) ms | β− | 158Nd | 5−# | ||||||||||||
159Pr | 59 | 100 | 158.95623(43)# | 134(43) ms | β− | 159Nd | 3/2−# | ||||||||||||
160Pr | 59 | 101 | 159.96114(43)# | 170(140) ms | β− | 160Nd | 1+# | ||||||||||||
161Pr | 59 | 102 | 160.96512(54)# | 90# ms [>550 ns] |
3/2−# | ||||||||||||||
This table header & footer: |
- ^ mPr – Excited nuclear isomer.
- ^ ( ) – Uncertainty (1σ) is given in concise form in parentheses after the corresponding last digits.
- ^ # – Atomic mass marked #: value and uncertainty derived not from purely experimental data, but at least partly from trends from the Mass Surface (TMS).
- ^ a b c # – Values marked # are not purely derived from experimental data, but at least partly from trends of neighboring nuclides (TNN).
- ^
Modes of decay:
EC: Electron capture IT: Isomeric transition
p: Proton emission - ^ Bold italics symbol as daughter – Daughter product is nearly stable.
- ^ Bold symbol as daughter – Daughter product is stable.
- ^ ( ) spin value – Indicates spin with weak assignment arguments.
- ^ Order of ground state and isomer is uncertain.
- ^ a b Fission product
References
edit- ^ a b c d Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S.; Audi, G. (2021). "The NUBASE2020 evaluation of nuclear properties" (PDF). Chinese Physics C. 45 (3): 030001. doi:10.1088/1674-1137/abddae.
- ^ "Standard Atomic Weights: Praseodymium". CIAAW. 2017.
- ^ Prohaska, Thomas; Irrgeher, Johanna; Benefield, Jacqueline; Böhlke, John K.; Chesson, Lesley A.; Coplen, Tyler B.; Ding, Tiping; Dunn, Philip J. H.; Gröning, Manfred; Holden, Norman E.; Meijer, Harro A. J. (2022-05-04). "Standard atomic weights of the elements 2021 (IUPAC Technical Report)". Pure and Applied Chemistry. doi:10.1515/pac-2019-0603. ISSN 1365-3075.
- ^ Wang, Meng; Huang, W.J.; Kondev, F.G.; Audi, G.; Naimi, S. (2021). "The AME 2020 atomic mass evaluation (II). Tables, graphs and references*". Chinese Physics C. 45 (3): 030003. doi:10.1088/1674-1137/abddaf.
- Isotope masses from:
- Audi, Georges; Bersillon, Olivier; Blachot, Jean; Wapstra, Aaldert Hendrik (2003), "The NUBASE evaluation of nuclear and decay properties", Nuclear Physics A, 729: 3–128, Bibcode:2003NuPhA.729....3A, doi:10.1016/j.nuclphysa.2003.11.001
- Half-life, spin, and isomer data selected from the following sources.
- Audi, Georges; Bersillon, Olivier; Blachot, Jean; Wapstra, Aaldert Hendrik (2003), "The NUBASE evaluation of nuclear and decay properties", Nuclear Physics A, 729: 3–128, Bibcode:2003NuPhA.729....3A, doi:10.1016/j.nuclphysa.2003.11.001
- National Nuclear Data Center. "NuDat 2.x database". Brookhaven National Laboratory.
- Holden, Norman E. (2004). "11. Table of the Isotopes". In Lide, David R. (ed.). CRC Handbook of Chemistry and Physics (85th ed.). Boca Raton, Florida: CRC Press. ISBN 978-0-8493-0485-9.