Noel Sydney Hush (15 December 1924 – 20 March 2019)[2] was an Australian chemist at the University of Sydney.[3][4]

Noel Hush
Hush in 2006
Born
Noel Sydney Hush

(1924-12-15)15 December 1924
Sydney, Australia
Died20 March 2019(2019-03-20) (aged 94)
NationalityAustralian, UK
Known forElectron transfer, molecular electronics, finite-field response
Awards
Scientific career
FieldsTheoretical chemistry, chemical physics
InstitutionsUniversity of Manchester, University of Bristol, University of Sydney
Thesis The electronic spectrum of pentacene in five states of ionization: theory and experiment
Doctoral advisors(DSc 1959) H.C. Longuet-Higgins FRS and M.H.L. Pryce FRS

Career

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Hush was born in Sydney on 15 December 1924 and obtained his BSc hons (1945) and MSc (1948) at the University of Sydney, where he worked as a research fellow in the Department of Chemistry (1945–49). He then accepted an invitation from M. G. Evans FRS to work in England as an assistant lecturer at the University of Manchester (1950–54) in the department created by Michael Polanyi. He was subsequently lecturer and then reader in the Department of Chemistry, University of Bristol (1955–71).

He returned to Australia in 1971 to found the Department of Theoretical Chemistry at the University of Sydney, the first such department in Australia. In 1989 he became a full-time research-only emeritus professor. He has held numerous prestigious visiting scientist positions at universities in Australia, the UK, and the US.[3]

Adiabatic electron transfer

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A unifying theme of Hush's research is explanation of chemical electron transfer. This is the basis of oxidation–reduction processes, which are ubiquitous in nature in both the inorganic and biological spheres. The mechanism of these reactions—the simplest of which proceed without making or breaking chemical bonds—remained unknown until the mid-1950s, when several independent theoretical studies showed that it was due to modulation of coupling between electronic and vibrational motions. According to his Royal Society election citation,[5] Hush's research in the area of homogeneous and heterogeneous electron transfer[6] showed that electron transfer occurring during a collision between a molecule and either another molecule or an electrode surface occurs adiabatically on a continuous potential-energy surface, and that electron transfer can occur by either optical or thermal mechanisms with the corresponding rates being closely connected.[7]

Awards

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See also

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References

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  1. ^ a b "Elsevier Announces the Winner of the 4th Ahmed Zewail Prize in Molecular Sciences".
  2. ^ "Passing of eminent scientist Professor Noel Hush". University of Sydney. 22 March 2019. Retrieved 22 March 2019.
  3. ^ a b "Hush, Noel Sydney (1924– )". Encyclopaedia of Australian Science. Retrieved 18 September 2015.
  4. ^ Faculty of Science – The University of Sydney
  5. ^ "Fellows Details". Royal Society. Retrieved 18 September 2015.
  6. ^ Hush, N. S. (1961). "Adiabatic theory of outer sphere electron-transfer reactions in solution". Transactions of the Faraday Society. 57: 577. doi:10.1039/TF9615700557.
  7. ^ Hush, N. S. (1967). "Intervalence-Transfer Absorption. Part 2. Theoretical Considerations and Spectroscopic Data". Intervalence-transfer absorption. II. Theoretical considerations and spectroscopic data. Progress in Inorganic Chemistry. Vol. 8. pp. 391–444. doi:10.1002/9780470166093.ch7. ISBN 9780470166093.