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Tailings

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In mining, tailings or tails are the materials left over after the process of separating the valuable fraction from the uneconomic fraction (gangue) of an ore. Tailings are different from overburden, which is the waste rock or other material that overlies an ore or mineral body and is displaced during mining without being processed.

The extraction of minerals from ore can be done two ways: placer mining, which uses water and gravity to concentrate the valuable minerals, or hard rock mining, which pulverizes the rock containing the ore and then relies on chemical reactions to concentrate the sought-after material. In the latter, the extraction of minerals from ore requires comminution, i.e., grinding the ore into fine particles to facilitate extraction of the target element(s). Because of this comminution, tailings consist of a slurry of fine particles, ranging from the size of a grain of sand to a few micrometres.[1] Mine tailings are usually produced from the mill in slurry form, which is a mixture of fine mineral particles and water.[2]

Tailings are likely to be dangerous sources of toxic chemicals such as heavy metals, sulfides and radioactive content. These chemicals are especially dangerous when stored in water in ponds behind tailings dams. These ponds are also vulnerable to major breaches or leaks from the dams, causing environmental disasters, such as the Mount Polley disaster in British Columbia. Because of these and other environmental concerns such as groundwater leakage, toxic emissions and bird death, tailing piles and ponds have received more scrutiny, especially in developed countries, but the first UN-level standard for tailing management was only established 2020.[3]

There are a wide range of methods for recovering economic value, containing or otherwise mitigating the impacts of tailings. However, internationally, these practices are poor, sometimes violating human rights.

Terminology

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Tailings are also called mine dumps, culm dumps, slimes, refuse, leach residue, slickens, or terra-cone (terrikon).[citation needed]

Examples

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Sulfide minerals

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The effluent from the tailings from the mining of sulfidic minerals has been described as "the largest environmental liability of the mining industry".[4] These tailings contain large amounts of pyrite (FeS2) and Iron(II) sulfide (FeS), which are rejected from the sought-after ores of copper and nickel, as well as coal. Although harmless underground, these minerals are reactive toward air in the presence of microorganisms, which if not properly managed lead to acid mine drainage.

 
Yellow boy in a stream receiving acid mine drainage from surface coal mining

Phosphate rock mining

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Phosphogypsum stack located near Fort Meade, Florida. These contain the waste byproducts of the phosphate fertilizer industry.

Between 100 million and 280 million tons of phosphogypsum waste are estimated to be produced annually as a consequence of the processing of phosphate rock for the production of phosphate fertilizers.[5] In addition to being useless and abundant, phosphogypsum is radioactive due to the presence of naturally occurring uranium and thorium, and their daughter isotopes. Depending on the price achievable on the uranium market, extraction of the uranium content may be economically lucrative even absent other incentives, such as reducing the harm the radioactive heavy metals do to the environment.

Aluminium

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Bauxite tailings is a waste product generated in the industrial production of aluminium. Making provision for the approximately 70 million tonnes (150 billion pounds) that is produced annually is one of the most significant problems for the aluminium mining industry.[6]

Red mud

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This section is an excerpt from Red mud.[edit]
 
Red mud near Stade (Germany)
 
Bauxite, an aluminium ore (Hérault department, France). The reddish colour is due to iron oxides that make up the main part of the red mud.

Red mud, now more frequently termed bauxite residue, is an industrial waste generated during the processing of bauxite into alumina using the Bayer process. It is composed of various oxide compounds, including the iron oxides which give its red colour. Over 97% of the alumina produced globally is through the Bayer process; for every tonne (2,200 lb) of alumina produced, approximately 1 to 1.5 tonnes (2,200 to 3,300 lb) of red mud are also produced; the global average is 1.23. Annual production of alumina in 2023 was over 142 million tonnes (310 billion pounds) resulting in the generation of approximately 170 million tonnes (370 billion pounds) of red mud.[7]

Due to this high level of production and the material's high alkalinity, if not stored properly, it can pose a significant environmental hazard. As a result, significant effort is being invested in finding better methods for safe storage and dealing with it such as waste valorization in order to create useful materials for cement and concrete.[8]

Less commonly, this material is also known as bauxite tailings, red sludge, or alumina refinery residues. Increasingly, the name processed bauxite is being adopted, especially when used in cement applications.

Coal

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This section is an excerpt from Coal refuse.[edit]
 
Coal waste in Pennsylvania

Coal refuse (also described as coal waste, rock, slag, coal tailings, waste material, rock bank, culm, boney, or gob[9]) is the material left over from coal mining, usually as tailings piles or spoil tips. For every tonne of hard coal generated by mining, 400 kg (880 lb) of waste material remains, which includes some lost coal that is partially economically recoverable.[10] Coal refuse is distinct from the byproducts of burning coal, such as fly ash.

 
Coal spoil stones

Piles of coal refuse can have significant negative environmental consequences, including the leaching of iron, manganese, and aluminum residues into waterways and acid mine drainage.[11] The runoff can create both surface and groundwater contamination.[12] The piles also create a fire hazard, with the potential to spontaneously ignite. Because most coal refuse harbors toxic components, it is not easily reclaimed by replanting with plants like beach grasses.[13][14]

Gob has about four times as much toxic mercury and more sulfur than typical coal.[9] Culm is the term for waste anthracite coal.[9]

Economics

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Early mining operations often did not take adequate steps to make tailings areas environmentally safe after closure.[15][16] Modern mines, particularly those in jurisdictions with well-developed mining regulations and those operated by responsible mining companies, often include the rehabilitation and proper closure of tailings areas in their costs and activities. For example, the Province of Quebec, Canada, requires not only the submission of a closure plan before the start of mining activity, but also the deposit of a financial guarantee equal to 100% of the estimated rehabilitation costs.[17] Tailings dams are often the most significant environmental liability for a mining project.[18]

Mine tailings may have economic value in carbon sequestration due to the large exposed surface area of the minerals.[19]

Environmental concerns

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The fraction of tailings to ore can range from 90 to 98% for some copper ores to 20–50% of the other (less valuable) minerals.[20] The rejected minerals and rocks liberated through mining and processing have the potential to damage the environment by releasing toxic metals (arsenic and mercury being two major culprits), by acid drainage (usually by microbial action on sulfide ores), or by damaging aquatic wildlife that rely on clear water (vs suspensions).[21]

Tailings ponds can also be a source of acid drainage, leading to the need for permanent monitoring and treatment of water passing through the tailings dam; the cost of mine cleanup has typically been 10 times that of mining industry estimates when acid drainage was involved.[22]

Disasters

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See also: List of tailings dam failures

The greatest danger of tailings ponds is dam failure, with the most publicized failure in the U.S. being the failure of a coal slurry dam in the West Virginia Buffalo Creek Flood of 1972, which killed 125 people; other collapses include the Ok Tedi environmental disaster in New Guinea, which destroyed the fishery of the Ok Tedi River. On average, worldwide, there is one big accident involving a tailings dam each year.[22]

Other disasters caused by tailings dam failures are, the 2000 Baia Mare cyanide spill and the Ajka alumina plant accident. In 2015, the iron ore tailings dam failure at the Germano mine complex in Minas Gerais, Brazil, was the country's biggest environmental disaster. The dam breach caused the death of 19 people due to flooding of tailings slime downstream and affected some 400 km of the Doce river system with toxic effluence and out into the Atlantic Ocean.

Human rights

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Tailings deposits tend to be located in rural areas or near marginalized communities, such as indigenous communities. The Global Industry Standard on Tailings Management recommends that "a human rights due diligence process is required to identify and address those that are most at risk from a tailings facility or its potential failure."[23]

Storage methods

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Historically, tailings were disposed of in the most convenient manner, such as in downstream running water or down drains. Because of concerns about these sediments in the water and other issues, tailings ponds came into use. The sustainability challenge in the management of tailings and waste rock is to dispose of material, such that it is inert or, if not, stable and contained, to minimise water and energy inputs and the surface footprint of wastes and to move toward finding alternate uses.[21]

Tailings dams and ponds

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Main article: Tailings dam

Bounded by impoundments (an impoundment is a dam), these dams typically use "local materials" including the tailings themselves, and may be considered embankment dams.[1] Traditionally, the only option for tailings storage was to contain the tailings slurry with locally available earthen materials.[24] This slurry is a dilute stream of the tailings solids within water that was sent to the tailings storage area. The modern tailings designer has a range of tailings products to choose from depending upon how much water is removed from the slurry prior to discharge. It is increasingly common for tailings storage facilities to require special barriers like Bituminous Geomembranes (BGMs) to contain liquid tailings slurries and prevent impact to the surrounding environment.[25] The removal of water not only can create a better storage system in some cases (e.g. dry stacking, see below) but can also assist in water recovery which is a major issue as many mines are in arid regions. In a 1994 description of tailings impoundments, however, the U.S. EPA stated that dewatering methods may be prohibitively expensive except in special circumstances.[1] Subaqueous storage of tailings has also been used.[1]

Tailing ponds are areas of refused mining tailings where the waterborne refuse material is pumped into a pond to allow the sedimentation (meaning separation) of solids from the water. The pond is generally impounded with a dam, and known as tailings impoundments or tailings dams.[1] It was estimated in 2000 that there were about 3,500 active tailings impoundments in the world.[18] The ponded water is of some benefit as it minimizes fine tailings from being transported by wind into populated areas where the toxic chemicals could be potentially hazardous to human health; however, it is also harmful to the environment. Tailing ponds are often somewhat dangerous because they attract wildlife such as waterfowl or caribou as they appear to be a natural pond, but they can be highly toxic and harmful to the health of these animals. Tailings ponds are used to store the waste made from separating minerals from rocks, or the slurry produced from tar sands mining. Tailings are sometimes mixed with other materials such as bentonite to form a thicker slurry that slows the release of impacted water to the environment.

There are many different subsets of this method, including valley impoundments, ring dikes, in-pit impoundments, and specially dug pits.[1] The most common is the valley pond, which takes advantage of the natural topographical depression in the ground.[1] Large earthen dams may be constructed and then filled with the tailings. Exhausted open pit mines may be refilled with tailings. In all instances, due consideration must be made to contamination of the underlying water table, amongst other issues. Dewatering is an important part of pond storage, as the tailings are added to the storage facility the water is removed – usually by draining into decant tower structures. The water removed can thus be reused in the processing cycle. Once a storage facility is filled and completed, the surface can be covered with topsoil and revegetation commenced. However, unless a non-permeable capping method is used, water that infiltrates into the storage facility will have to be continually pumped out into the future.

Paste tailings

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Paste tailings is a modification to the conventional methods of disposal of tailings (pond storage). Conventional tailings slurries are composed of a low percent of solids and relatively high water content (normally ranging from 20% to 60% solids for most hard rock mining) and when deposited into the tailings pond the solids and liquids separate. In paste tailings the percent of solids in the tailings slurry is increased through the use of paste thickeners to produce a product where the minimal separation of water and solids occurs and the material is deposited into a storage area as a paste (with a consistency somewhat like toothpaste). Paste tailings has the advantage that more water is recycled in the processing plant and therefore the process is more water efficient than conventional tailings and there is a lower potential for seepage. However the cost of the thickening is generally higher than for conventional tailings and the pumping costs for the paste are also normally higher than for conventional tailings as positive displacement pumps are normally required to transport the tailings from the processing plant to the storage area. Paste tailings are used in several locations around the world including Sunrise Dam in Western Australia and Bulyanhulu Gold Mine in Tanzania.[26]

Dry stacking

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Tailings do not have to be stored in ponds or sent as slurries into oceans, rivers or streams. There is a growing use of the practice of dewatering tailings using vacuum or pressure filters so the tailings can then be stacked.[27] This saves water which potentially reduces the impacts on the environment in terms of a reduction in the potential seepage rates, space used, leaves the tailings in a dense and stable arrangement and eliminates the long-term liability that ponds leave after mining is finished. However although there are potential merits to dry stacked tailings these systems are often cost prohibitive due to increased capital cost to purchase and install the filter systems and the increase in operating costs (generally associated electricity consumption and consumables such as filter cloth) of such systems.[citation needed]

Storage in underground workings

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While disposal into exhausted open pits is generally a straightforward operation, disposal into underground voids is more complex. A common modern approach is to mix a certain quantity of tailings with waste aggregate and cement, creating a product that can be used to backfill underground voids and stopes. A common term for this is high density paste fill (HDPF). HDPF is a more expensive method of tailings disposal than pond storage, however it has many other benefits as it can significantly increase the stability of underground excavations by providing a means for ground stress to be transmitted across voids – rather than having to pass around them – which can cause mining induced seismic events like that suffered previously at the Beaconsfield Mine Disaster.

Riverine tailings

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Usually called riverine tailings disposal (RTD). In most environments, not a particularly environmentally sound practice, it has seen significant utilisation in the past, leading to such spectacular environmental damage as done by the Mount Lyell Mining and Railway Company in Tasmania to the King River, or the poisoning from the Panguna mine on Bougainville Island, which led to large-scale civil unrest on the island, and the eventual permanent closing of the mine.[22]

As of 2005, only three mines operated by international companies continued to use river disposal: The Ok Tedi mine, the Grasberg mine[22] and the Porgera mine, all on New Guinea. This method is used in these cases due to seismic activity and landslide dangers which make other disposal methods impractical and dangerous.

Submarine tailings

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Commonly referred to as STD (Submarine Tailings Disposal) or DSTD (Deep Sea Tailings Disposal). Tailings can be conveyed using a pipeline then discharged so as to eventually descend into the depths. Practically, it is not an ideal method, as the close proximity to off-shelf depths is rare. When STD is used, the depth of discharge is often comparatively shallow, and extensive damage to the seafloor can result due to covering by the tailings product.[28] If the density and temperature of the tailings product is not controlled, it may travel long distances, or even float to the surface.

This method is used by the gold mine on Lihir Island; its waste disposal has been viewed by environmentalists[who?] as highly damaging, while the owners claim that it is not harmful.[22]

Phytostabilisation

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Phytostabilisation is a form of phytoremediation that uses hyperaccumulator plants for long-term stabilisation and containment of tailings, by sequestering pollutants in soil near the roots. The plant's presence can reduce wind erosion, or the plant's roots can prevent water erosion, immobilise metals by adsorption or accumulation, and provide a zone around the roots where the metals can precipitate and stabilise. Pollutants become less bioavailable and livestock, wildlife, and human exposure is reduced. This approach can be especially useful in dry environments, which are subject to wind and water dispersion.[29]

Different methods

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Considerable effort and research continues to be made into discovering and refining better methods of tailings disposal. Research at the Porgera Gold Mine is focusing on developing a method of combining tailings products with coarse waste rock and waste muds to create a product that can be stored on the surface in generic-looking waste dumps or stockpiles. This would allow the current use of riverine disposal to cease. Considerable work remains to be done. However, co-disposal has been successfully implemented by several designers including AMEC at, for example, the Elkview Mine in British Columbia.

Pond reclamation by microbiology

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During extraction of the oil from oil sand, tailings consisting of water, silt, clays and other solvents are also created. This solid will become mature fine tailings by gravity. Foght et al (1985) estimated that there are 103 anaerobic heterotrophs and 104 sulfate-reducing prokaryotes per milliliter in the tailings pond, based on conventional most probable number methods. Foght set up an experiment with two tailings ponds and an analysis of the archaea, bacteria, and the gas released from tailings ponds showed that those were methanogens. As the depth increased, the moles of CH4 released actually decreased.[30]

Siddique (2006, 2007) states that methanogens in the tailings pond live and reproduce by anaerobic degradation, which will lower the molecular weight from naphtha to aliphatic, aromatic hydrocarbons, carbon dioxide and methane. Those archaea and bacteria can degrade the naphtha, which was considered as waste during the procedure of refining oil. Both of those degraded products are useful. Aliphatic, aromatic hydrocarbons and methane can be used as fuel in the humans' daily lives. In other words, these methanogens improve the coefficient of utilization. Moreover, these methanogens change the structure of the tailings pond and help the pore water efflux to be reused for processing oil sands. Because the archaea and bacteria metabolize and release bubbles within the tailings, the pore water can go through the soil easily. Since they accelerate the densification of mature fine tailings, the tailings ponds are enabled to settle the solids more quickly so that the tailings can be reclaimed earlier. Moreover, the water released from the tailings can be used in the procedure of refining oil. Reducing the demand of water can also protect the environment from drought.[31]

Reprocessing

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As mining techniques and the price of minerals improve, it is not unusual for tailings to be reprocessed using new methods, or more thoroughly with old methods, to recover additional minerals. Extensive tailings dumps of Kalgoorlie / Boulder in Western Australia were re-processed profitably in the 1990s by KalTails Mining.[32]

A machine called the PET4K Processing Plant has been used in a variety of countries for the past 20 years to remediate contaminated tailings.[33]

International policy

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The UN and business communities developed an international standard for tailings management in 2020 after the critical failure of the Brumadinho dam disaster.[3] The program was convened by United Nations Environment Programme (UNEP), International Council on Mining and Metals (ICMM) and the Principles for Responsible Investment.[3]

See also

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References

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  1. ^ a b c d e f g US EPA. (1994). Technical Report: Design and Evaluation of Tailings Dams Archived 10 May 2013 at the Wayback Machine.
  2. ^ Zvereva, V. P.; Frolov, K. R.; Lysenko, A. I. (13 October 2021). "Chemical reactions and conditions of mineral formation at tailings storage facilities of the Russian Far East". Gornye Nauki I Tekhnologii = Mining Science and Technology (Russia). 6 (3): 181–191. doi:10.17073/2500-0632-2021-3-181-191. ISSN 2500-0632. S2CID 243263530.
  3. ^ a b c "Mining industry releases first standard to improve safety of waste storage". Mongabay Environmental News. 6 August 2020. Retrieved 16 April 2021.
  4. ^ Nehdi, Moncef; Tariq, Amjad "Stabilization of sulphidic mine tailings for prevention of metal release and acid drainage using cementitious materials: a review" Journal of Environmental Engineering and Science (2007), 6(4), 423–436. doi:10.1139/S06-060
  5. ^ Tayibi, Hanan; Choura, Mohamed; López, Félix A.; Alguacil, Francisco J.; López-Delgado, Aurora (2009). "Environmental Impact and Management of Phosphogypsum". Journal of Environmental Management. 90 (8): 2377–2386. Bibcode:2009JEnvM..90.2377T. doi:10.1016/j.jenvman.2009.03.007. hdl:10261/45241. PMID 19406560.
  6. ^ Ayres, R. U., Holmberg, J., Andersson, B., "Materials and the global environment: Waste mining in the 21st century", MRS Bull. 2001, 26, 477. doi:10.1557/mrs2001.119
  7. ^ Annual statistics collected and published by World Aluminium Archived 2019-10-21 at the Wayback Machine.
  8. ^ Evans, K., "The History, Challenges and new developments in the management and use of Bauxite Residue", J. Sustain Metall. May 2016. doi:10.1007/s40831-016-00060-x.
  9. ^ a b c "Waste Coal | Energy Justice Network". www.energyjustice.net. Retrieved 2 August 2020.
  10. ^ Fecko, P.; Tora, B.; Tod, M. (1 January 2013), Osborne, Dave (ed.), "3 - Coal waste: handling, pollution impacts and utilization", The Coal Handbook: Towards Cleaner Production, Woodhead Publishing Series in Energy, vol. 2, Woodhead Publishing, pp. 63–84, ISBN 978-1-78242-116-0, retrieved 2 August 2020
  11. ^ "Waste Coal | Energy Justice Network". www.energyjustice.net. Retrieved 2 August 2020.
  12. ^ Kowalska, Arlena, et al., "VLF mapping and resistivity imaging of contaminated quaternary formations near to 'Panewniki' coal waste disposal (Southern Poland)." Acta Geodynamica et Geromaterialia, vol. 9, no. 4, 2012, p. 473+. Gale Academic OneFile, http://link-gale-c.m.wikipedialibrary.idm.oclc.org/apps/doc/A311377866/GPS?u=wikipedia&sid=GPS&xid=f0f488c8. Accessed 7 Aug. 2020.
  13. ^ POWER (1 July 2016). "The Coal Refuse Dilemma: Burning Coal for Environmental Benefits". POWER Magazine. Retrieved 2 August 2020.
  14. ^ Dove, D.; Daniels, W.; Parrish, D. (1990). "Importance of Indigenous VAM Fungi for the Reclamation of Coal Refuse Piles". Journal American Society of Mining and Reclamation. 1990 (1): 463–468. doi:10.21000/jasmr90010463. ISSN 2328-8744.
  15. ^ "Archived copy". Archived from the original (PDF) on 20 May 2020. Retrieved 1 October 2012.{{cite web}}: CS1 maint: archived copy as title (link)
  16. ^ Adler, Rebecca A.; Claassen, Marius; Godfrey, Linda; Turton, Anthony R. (July 2007). "Water, mining, and waste: an historical and economic perspective on conflict management in South Africa" (PDF). The Economics of Peace and Security Journal. 2 (2). doi:10.15355/epsj.2.2.33. Archived from the original (PDF) on 26 December 2010. Retrieved 19 May 2020.
  17. ^ Ministry of Natural Resources and Wildlife, "Bill 14: creating a foundation for an innovative mining development model"
  18. ^ a b TE Martin, MP Davies. (2000). Trends in the stewardship of tailings dams.
  19. ^ Wilson, Siobhan A. (2009). "Carbon Dioxide Fixation within Mine Wastes of Ultramafic-Hosted Ore Deposits: Examples from the Clinton Creek and Cassiar Chrysotile Deposits, Canada". Economic Geology. 104 (1): 95–112. Bibcode:2009EcGeo.104...95W. doi:10.2113/gsecongeo.104.1.95.
  20. ^ D. R. Nagaraj "Minerals Recovery and Processing" in Kirk-Othmer Encyclopedia of Chemical Technology, Wiley-VCH doi:10.1002/0471238961.1309140514010701.a01.pub2
  21. ^ a b Franks, DM, Boger, DV, Côte, CM, Mulligan, DR. 2011. Sustainable Development Principles for the Disposal of Mining and Mineral Processing Wastes. Resources Policy. Vol. 36. No. 2. pp 114–122
  22. ^ a b c d e Jared Diamond (2005). Collapse. Penguin. ISBN 9780143036555., page 452–458
  23. ^ "Global Industry Standard on Tailings Management – Global Tailings Review". globaltailingsreview.org. Retrieved 16 April 2021.
  24. ^ "What are Tailings?" (PDF). smenet.org. Society for Mining, Metallurgy & Exploration. February 2021.
  25. ^ Breul, B.; McIlwraith, R. (2015). Bituminous Geomembranes in Mine Construction. Tailings and Mine Waste Management for the 21st Century 2015. The Australasian Institute of Mining and Metallurgy. P201506036.
  26. ^ Theriault, J. A.; Frostiak, J.; Welch, D., Surface Disposal of Paste Tailings at the Bulyanhulu Gold Mine, Tanzania
  27. ^ Davies, M. P.; Rice, S. (16–19 January 2001). An alternative to conventional tailing management - "dry stack" filtered tailings. Proceedings of the Eighth International Conference on Tailings and Mine Waste. Fort Collins, Colorado, US: Balkema. pp. 411–422.
  28. ^ Association, California Mining (1991). Mine waste management. Chelsea, Mich.: Lewis Publishers. ISBN 9780873717465.
  29. ^ Mendez MO, Maier RM (2008). "Phytostabilization of Mine Tailings in Arid and Semiarid Environments—An Emerging Remediation Technology". Environ Health Perspect. 116 (3): 278–83. doi:10.1289/ehp.10608. PMC 2265025. PMID 18335091.
  30. ^ Foght, J.M., Fedorak, P.M., Westlake, D.W.S., and Boerger, H.J. 1985. Microbial content and metabolic activities in the Syncrude tailings pond. AOSTRA J. Res. 1: 139–146.
  31. ^ Holowenko, F.M.; MacKinnon, M.D.; Fedorak, P.M. (2000). "Methanogens and sulfate-reducing bacteria in oil sands fine tailings waste". Can. J. Microbiol. 46 (10): 927–937. doi:10.1139/cjm-46-10-927. PMID 11068680.
  32. ^ J.Engels & D.Dixon-Hardy. "Kaltails project, Kalgoorlie, Western Australia". Archived from the original on 24 January 2010. Retrieved 19 October 2009.
  33. ^ Smith, Mike (25 September 2017). "Can African machine produce a promising future in Butte?". Missoulian. Retrieved 25 September 2017.
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